PAM is uncompressed and few everyday apps open it. PDF looks the same on every device and keeps several pages in one file. PAM is at home in image-processing pipelines that need an alpha channel; PDF is the usual choice for documents that must look the same everywhere, and printing.
Add several files and you can also combine them into a single PDF. The defaults suit most files. Under Options you can choose the page size.
Pictures with more than 8 bits per channel are reduced to 8 bits when they are decoded. Each picture becomes one page. The page can match the picture's own size or be A4 or US Letter; on paper the sheet turns to suit the picture, which is shrunk to fit inside the margins and never enlarged.